io_uring: don't mark link's head for_async

No reason to mark a head of a link as for-async in io_req_defer_prep().
grab_env(), etc. That will be done further during submission if
neccessary.

Mark for_async=false saving extra grab_env() in many cases.

Signed-off-by: Pavel Begunkov <asml.silence@gmail.com>
Signed-off-by: Jens Axboe <axboe@kernel.dk>